Depends what prescriptions she is filling for you. "Pharmacist: is it true this Viagra will work for hours?"
But seriously: just go ask her. Start up some small talk. See if you can direct the conversation to some common element, then suggest going out to do that together? Or get her talking and then acknowledge she is at work by saying "hey, I'd like to hear more about it but I can see you're getting busy. Can I come by for you after work and we can talk more over a cup of coffee/tea?"
How about this to get her alone: wait till she hands you the medication and then talk in a hushed voice and say "there's something private I needed to know. Can you step aside <look at her coworkers> for a moment?" She won't resist because you might be asking a personal medical question. Then immediately ask her out. This way you're not getting her in trouble for socializing while working.
If she has a boyfriend, she'll say so, but you'll never know until you ask her.
Good luck! Please let us know how it goes.
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