I'm a fanatic for electronica, ran a nightclub here in Syd and alot of my friends are big DJs here in the scene.
Electronica is so broad, every genre has a hundred sub genres, you need to find a genre you like and go from there.
Shpongle - Tales of the Inexpressible, (seen Simon Posford and Raja Ram live, they are two of the most talented musicians on earth.)
Try and get a hold of Sasha and Digweeds Northern Exposure
Amazon.com: Northern Exposure, Vol. 1: Sasha & John Digweed: Music
Sasha - Airdrawndagger
Sasha - Involver
James Holden - Balance 005
James Holden - At the Controls
the two best mixes to come out recently, "Joris Voorn - Resident Adviser Podcast" IMO Joris Voorn is the best DJ on the planet today, he fuses techno with soulful house i have seen him live a few times and he never disapoints
the new Balance CD by SOS is also amazing.